Of course, the number one thing you want to look at is the commission rate. What percentage of the customer’s payment will you receive? In some cases, there is a flat fee for every sale made, and sometimes you will get a percentage of the total sale. Keep your eye out for "percentage of commission" sales, as this means that you're not taking a percentage of the total sale, but rather a percentage of the company's commission.

Since July 2014 I read for the first time about affiliate marketing, I never heard of this way of working before. Until then, I have worked in MLM (multi-level-marketing). Which wasn't that suitable for me. MLM is a very aggressive way of marketing, and you do need to harass everyone around you to join. That's not quite me. Affiliate marketing works very different. You write reviews about products of a company, and when people decide to buy something after reading your review, you get a few percentage of the sale. That's more my line of work.
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Now most affiliate programs have strict terms and conditions on how the lead is to be generated. There are also certain methods that are outright banned, such as installing adware or spyware that redirect all search queries for a product to an affiliate's page. Some affiliate marketing programs go as far as to lay out how a product or service is to be discussed in the content before an affiliate link can be validated.
It’s important to know where your traffic is coming from and the demographics of your audience. This will allow you to customize your messaging so that you can provide the best affiliate product recommendations. You shouldn’t just focus on the vertical you’re in, but on the traffic sources and audience that’s visiting your site. Traffic sources may include organic, paid, social media, referral, display, email, or direct traffic. You can view traffic source data in Google Analytics to view things such as time on page, bounce rate, geo location, age, gender, time of day, devices (mobile vs. desktop), and more so that you can focus your effort on the highest converting traffic. This analytics data is crucial to making informed decisions, increasing your conversion rates, and making more affiliate sales. 
Amazon's commission rate is pennies from each dollar of merchandise that you sell. What many people don't know is that there are affiliate opportunities out there that pay commission rates that are much more favorable, from $20-$100 (and even more). Browse affiliate networks like Commission Junction, Share-a-Sale, Rakuten and Ejunkie for opportunities and their general commission rate.